Efficient ortho–para hydrogen conversion is essential to suppress spontaneous heat release and boil-off losses during cryogenic liquid hydrogen storage and pre-liquefaction processes. In this study, a novel catalyst-filled wavy plate-fin heat exchanger (CFHE) is proposed to simultaneously enhance heat transfer and ortho–para hydrogen conversion under cryogenic conditions. Compared with conventional straight-fin configurations, the wavy-fin structure introduces controlled flow perturbations and increased specific surface area, thereby intensifying transport processes. Three-dimensional computational fluid dynamics (CFD) simulations, using the SST k–ω turbulence model, coupled with an ortho–para hydrogen conversion kinetic model were performed to quantitatively investigate the effects of key geometric parameters and catalyst loading on hydrogen conversion, heat transfer, and pressure drop within a Reynolds number range of 941–1577 and a temperature range of 35–20 K. Within the same CFHE configuration, the para-hydrogen fraction remains nearly unchanged without catalyst but increases significantly with catalyst loading. However, the catalyst reduces the global average Colburn j-factor by about 25%. Despite higher friction losses, the outlet–inlet temperature difference decreases to about 0.866 times that of the non-catalyst case, indicating improved temperature uniformity. A comprehensive performance index e, integrating heat transfer enhancement, flow resistance, and conversion efficiency, was introduced and optimized using a genetic algorithm. The optimized CFHE achieves an outlet para-hydrogen fraction exceeding 95% of the thermodynamic equilibrium value while maintaining hydrogen entirely in the gaseous phase to avoid catalyst deactivation. Overall, the catalyst-packed wavy channel configuration demonstrates superior conversion efficiency, enhanced thermal uniformity, and improved overall performance compared with straight-fin structures, providing quantitative design guidance for high-performance heat exchangers in cryogenic hydrogen liquefaction systems.
Yan et al. (Wed,) studied this question.