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March 17, 2026Environmental Technology & Innovation3 citationsOpen Access

Valorization of Phosphogypsum into Carbon-Neutral Lime for Soil Lead Immobilization

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BPByung Jun ParkSNSeong Hyeon NamSJSeok Soon Jeong

Key Points

  • The aim is to develop a carbon-neutral technology for producing lime from phosphogypsum waste to immobilize soil lead.
  • Synthesized hydrated lime from phosphogypsum via alkaline conversion without CO2 release
  • Compared performance of synthesized lime with commercial hydrated lime
  • Evaluated lead removal efficiency in aqueous systems and Pb-contaminated soils
  • Measured effects on soil pH, phytoavailable lead, microbial activity, and plant growth
  • Achieved >95% lead removal in aqueous systems at pH ≥3
  • Increased soil pH from 5.6 to 9.4 in contaminated soils
  • Reduced phytoavailable lead by up to 99.6%
  • Enhanced microbial activity by 40%
  • Decreased lead uptake by lettuce by 82% while increasing plant biomass by 17% at optimal rates

Abstract

Conventional hydrated lime (Ca(OH) 2 ) is widely applied to immobilize heavy metals in soils but is associated with substantial CO 2 emissions during limestone calcination. This study presents a carbon-neutral waste valorization technology that converts phosphogypsum waste into hydrated lime (HLPG) via alkaline conversion without CO 2 release. The synthesized HLPG was fully transformed into Ca(OH) 2 and exhibited physicochemical properties comparable to commercial hydrated lime (CHL). In aqueous systems, HLPG achieved >95% Pb 2+ removal at pH ≥3, matching CHL performance. In Pb-contaminated soil, HLPG increased soil pH from 5.6 to 9.4, reduced phytoavailable Pb by up to 99.6%, enhanced microbial activity by 40%, decreased Pb uptake by lettuce by 82%, and increased plant biomass by 17% at optimal application rates. By integrating waste valorization, carbon-neutral lime production, and effective soil remediation , this technology offers a scalable and sustainable solution for managing Pb-contaminated soils while mitigating greenhouse gas emissions. • -Hydrated lime from phosphogypsum (HLPG) was synthesized without CO 2 emission • -HLPG showed comparable Pb removal efficiency to commercial hydrated lime • -HLPG significantly reduced Pb phytoavailability while enhancing lettuce growth • -HLPG offers a sustainable and carbon-neutral alternative for soil remediation

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Cite This Study

Park et al. (2026) studied this question.

synapsesocial.com/papers/69b8ef52deb47d591b8c56bchttps://doi.org/10.1016/j.eti.2026.104879
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