Reaction Channels of Iron-Oxo and Iron-Imido Molecular Intermediates

Thomas D. Jones; Henry R. Brothers; Elokkin Pate-Geames; David H. Jenkins; Konstantinos D. Vogiatzis

doi:10.1039/d5dt02942b

January 1, 2026Dalton TransactionsOpen Access

Reaction Channels of Iron-Oxo and Iron-Imido Molecular Intermediates

View Full Paper

Ask AI

Bookmark

Share

Key Points

The aim is to explore the reaction channels of iron-oxo and iron-imido intermediates in catalytic cycles.
Analyzed reaction pathways involving iron-oxo and iron-imido species
Utilized biomimetic models for simulations and comparisons
Investigated enzymatic cycles in non-heme contexts
Identified key oxidizing roles of iron-oxo intermediates
Showed that iron-imido intermediates can facilitate complex reactions
Found that both types of intermediates significantly impact catalytic efficiency

Implication

Examines reaction mechanisms of iron-oxo and iron-imido intermediates, indicating their role in catalysis.

Abstract

Non-heme Fe(IV)-oxo intermediates are integral components of many enzymatic and homogeneous catalytic cycles, where they serve as key oxidants that enable challenging transformations. Numerous studies have focused on developing biomimetic...

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Jones et al. (2026) studied this question.

synapsesocial.com/papers/69ba43984e9516ffd37a50a1 https://doi.org/10.1039/d5dt02942b

View Full Paper

Ask AI

Bookmark

Share

Reaction Channels of Iron-Oxo and Iron-Imido Molecular Intermediates

Key Points

Implication

Abstract

Discussion

Cite This Study

Reaction Channels of Iron-Oxo and Iron-Imido Molecular Intermediates

Key Points

Implication

Abstract

Discussion

Cite This Study

Keep reading

Keep reading