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March 19, 2026ChemistrySelect3 citations

Visible Light‐Driven Degradation of Levofloxacin by Europium‐Doped Zinc Bismuth Spinel Oxide

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MRMaryam RaoAAAdnan AshrafMNMuhammad Naeem

Key Points

  • The aim is to explore the effectiveness of europium-doped zinc bismuth spinel oxides in degrading levofloxacin under visible light.
  • Synthesized europium-doped zinc bismuth spinel oxides via hydrothermal method.
  • Characterized materials using FTIR, UV–vis spectroscopy, SEM–EDX, and XRD.
  • Investigated photocatalytic activity by varying irradiation time, pH, catalyst dosage, and drug concentration.
  • Achieved up to 93.39% removal of levofloxacin in 120 min under visible-light irradiation.
  • Indicated progressive band gap narrowing with europium doping, enhancing visible-light absorption.

Abstract

ABSTRACT Semiconductor photocatalysis is a widely employed strategy for the effective removal of pollutants from wastewater. Among various semiconductors, AB 2 X 4 ‐type spinel compounds have appeared as a promising class of advanced catalytic materials for drug degradation. In the present study, europium‐doped zinc bismuth spinel oxides were synthesized via a hydrothermal method. Europium doping introduces lattice defects and reduces the band gap, thereby enhancing visible‐light absorption and improving photocatalytic performance. The synthesized spinel oxides were characterized by FTIR, UV–vis spectroscopy, SEM–EDX, and XRD analyses, which confirmed their structural and optical features. The photocatalytic activity was systematically investigated by varying key operational parameters, including irradiation time, solution pH, catalyst dosage, and initial drug concentration. The optical band gaps of the ZBO‐ and Eu‐doped ZBO catalysts were 2.73, 2.42, 2.22 and 2.38 eV, respectively, indicating a progressive narrowing of the band gap upon Eu doping. Optimization studies demonstrated that up to 93.39% levofloxacin (LVF) removal efficiency could be achieved using 0.5 g/L catalyst in a 10 ppm LVF solution at neutral pH (≈7) within 120 min under visible‐light irradiation.

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Cite This Study

Rao et al. (2026) studied this question.

synapsesocial.com/papers/69bb9279496e729e6297fc66https://doi.org/10.1002/slct.202507114
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