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March 21, 2026Polymers2 citationsOpen Access

Static and Cyclic Mechanical Behavior of 3D-Printed PEEK Under Tensile and Compressive Loads

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FPFrancisco PinaCVCarlos M. S. VicenteJNJoaquim Justino Netto

Key Points

  • Assess the static and dynamic mechanical performance of 3D-printed PEEK, focusing on its fatigue behavior under compression.
  • Conducted tensile and compression tests on 3D-printed PEEK specimens with ±45° raster orientation.
  • Performed annealing at 270 °C for 5 hours to evaluate changes in crystallinity and mechanical properties.
  • Utilized micro-CT analysis to assess pore size changes post-annealing.
  • Executed compression-compression fatigue tests at varying frequencies and stress amplitudes.
  • Annealing increased crystallinity from 34.4% to 41.4% but reduced tensile strength from 60.8 MPa to 47.3 MPa.
  • Young's modulus increased from 2.51 GPa to 3.51 GPa after annealing.
  • Static compression strength improved from 80.1 MPa to 126.7 MPa post-annealing.
  • Fatigue tests revealed annealed specimens achieved infinite life at 83.3 MPa, indicating enhanced performance under cyclic loading.

Abstract

Polyether ether ketone (PEEK) is a high-performance polymer with exceptional mechanical properties, durability and lightweight. 3D printing of PEEK can be very beneficial in the medical industry to manufacture patient-specific implants; however, there is a lack of studies regarding the fatigue behavior of 3D-printed PEEK, especially under compression, which is closely related to its potential applications. This paper investigates the static and dynamic mechanical performance of 3D-printed PEEK. Tensile and compression tests were conducted on specimens with ±45° raster orientation. Annealing at 270 °C for 5 h increased crystallinity from 34.4% to 41.4% yet unexpectedly reduced tensile strength from 60.8 MPa to 47.3 MPa, while increasing Young’s modulus from 2.51 GPa to 3.51 GPa. Micro-CT analysis revealed increased pore size after annealing. Static compression strength showed improvement post-annealing, increasing from 80.1 MPa to 126.7 MPa, with modulus rising from 1.64 GPa to 2.28 GPa. Compression–compression fatigue tests, performed at 5 Hz and 2.5 Hz with stress amplitudes of 70–95% of maximum strength (R = 0.1), enabled the construction of the first S-N curve for 3D-printed PEEK under compressive loading. Annealed specimens exhibited superior fatigue life, with infinite life achieved at 83.3 MPa (70% of static strength). Thermal imaging highlighted the role of temperature in fatigue failure, showing that annealed specimens endured higher thermal loads. These findings support the suitability of 3D-printed PEEK for load-bearing biomedical applications under cyclic compressive loads.

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Cite This Study

Pina et al. (2026) studied this question.

synapsesocial.com/papers/69be362d6e48c4981c674e94https://doi.org/10.3390/polym18060748
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