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March 21, 2026CrystEngComm2 citations

Atom orientation in the SBU induced conformational isomerism in the hydroxamate-based In-MOFs

CYChangmeng YangYBYingxiang BaiRSRuwei Shen

Key Points

  • The aim is to explore conformational isomerism in hydroxamate-based metal-organic frameworks (MOFs).
  • Identified hydroxamate-based MOFs exhibiting conformational isomerism.
  • Analyzed atomic orientations within the frameworks.
  • Compared findings with carboxylate-based MOFs.
  • Demonstrated a rare case of conformational isomerism in hydroxamate-based MOFs.
  • Provided insights into the structural characteristics that lead to isomerism.
  • Indicated potential for new applications in material design.

Abstract

Although conformational isomerism is a common phenomenon in carboxylate-based metal-organic frameworks (MOFs), the conformational isomers of hydroxamate-based MOFs are still scarce. Herein, we report a rare example of conformational isomerism...

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Cite This Study

Yang et al. (2026) studied this question.

synapsesocial.com/papers/69be37506e48c4981c676d19https://doi.org/10.1039/d6ce00133e
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