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March 21, 2026Chemical Communications3 citations

D ● –A Radicals Fabricated from Polychlorinated Trityl and Pyridinium Featuring a SOMO–LUMO Electronic Transition

JLJingwen LiZZZiqi ZhangZLZenghui Li

Key Points

  • This research aims to create new D radicals by combining specific donor and acceptor molecules.
  • Synthesis of D radicals 2a–2c using polychlorinated trityl and pyridinium.
  • Characterization of electronic properties to analyze the SOMO–LUMO transition.
  • The introduction of pyridinium reduces LUMO energy significantly.
  • The newly synthesized radicals exhibit notable electronic properties.

Abstract

D ● –A radicals 2a–2c were developed by combining a polychlorinated trityl as donor with a pyridinium as acceptor. The electron-deficient nature of the pyridinium unit significantly lowers LUMO energy, thereby enabling...

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Cite This Study

Li et al. (2026) studied this question.

synapsesocial.com/papers/69be37626e48c4981c676f2ahttps://doi.org/10.1039/d6cc00928j
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