Experimental Evaluation of an Energy Generation and Storage System Based on a Concentration Redox Flow Battery Coupled to Solar Power

The increasing integration of renewable energy sources, such as solar photovoltaics, requires low-cost, scalable energy storage solutions suitable for decentralized systems. This work experimentally evaluates an iron chloride concentration redox flow battery (FeCl-CFB) coupled to a photovoltaic system. The battery, which employs the Fe2+/Fe3+ redox couple to store energy through a chemical concentration gradient, was electrochemically characterized using different carbon-based electrode materials and operated under solar charging for 25 charge–discharge cycles. A maximum power density of 6.3 W·m−2 was achieved at the cell level, with stable cycling behavior under variable solar irradiance. Coulombic and energy efficiencies remained within ranges of 63–72% and 20–28%, respectively, throughout the cycles. Despite these moderate efficiencies, the system demonstrated a consistent and functional usable capacity. The main limitation identified was a decrease in maximum power after prolonged cycling, attributable to resistance and polarization losses rather than electrolyte instability. These preliminary results characterize the initial performance of the FeCl-CFB under solar-driven conditions, highlighting significant efficiency and stability challenges that must be addressed through further optimization to determine the future potential for decentralized energy storage.