Electrochemically Cooperative Halogen Cation Delivery Enables Modular Electrophilic Haloesterification of Both Activated and Unactivated Alkenes

Key Points

• The study aims to develop a more versatile method for haloesterification of both activated and unactivated alkenes.
• Utilized electrochemical delivery of halogen cations to facilitate ester synthesis.
• Explored the reactivity of different types of alkenes, including electron-deficient variants.
• Demonstrated the process using a range of reactions to assess modularity and efficiency.
• Successfully haloesterified both activated and unactivated alkenes.
• Showed improved reaction conditions leading to higher yields for electron-deficient alkenes.
• Outlined the potential of this method for expanding applications in organic chemistry.