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March 22, 2026Hydrogen2 citationsOpen Access

Hydrogen Production from Blended Waste Biomass: Pyrolysis, Thermodynamic-Kinetic Analysis and AI-Based Modelling

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SKSana KordoghliASAbdelhakim SettarOBOumayma Belaati

Key Points

  • This work aims to explore hydrogen production from underutilized biomass through pyrolysis and AI-based process optimization.
  • Conducted proximate, ultimate, fibre, TGA/DTG analysis of pure biomass and blends.
  • Evaluated activation energy of different blends for hydrogen yield.
  • Applied kinetic modelling using isoconversional methods to analyze processes.
  • Blend 3 showed the highest hydrogen yield potential but the highest activation energy (Ea: 313.24 kJ/mol).
  • Blend 1 had the best activation energy value (Ea: 161.75 kJ/mol).
  • KAS method was identified as the most accurate for kinetic modelling.

Abstract

This work contributes to advancing sustainable energy and waste management strategies by investigating the thermochemical conversion of food-based biomass through pyrolysis, highlighting the role of artificial intelligence (AI) in enhancing process modelling accuracy and optimization efficiency. The main objective is to explore the potential of underutilized biomass resources like spent coffee grounds (SCGs) and DSs (date seeds) for sustainable hydrogen production. Specifically, it aims to optimize the pyrolysis process while evaluating the performance of these resources both individually and as blends. Proximate, ultimate, fibre, TGA/DTG, kinetic, thermodynamic, and Py-Micro-GC analyses were conducted for pure DS, SCG, and blends (75% DS-25% SCG, 50%DS-50%SCG, 25%DS–75%SCG). Blend 3 offered superior hydrogen yield potential but had the highest activation energy (Ea: 313.24 kJ/mol), while Blend 1 exhibited the best activation energy value (Ea: 161.75 kJ/mol). The kinetic modelling based on isoconversional methods (KAS, FWO, and Friedman) identified KAS as the most accurate. These approaches work together to provide a detailed understanding of the pyrolysis process with a particular emphasis on the integration of artificial intelligence (AI). An LSTM model trained with lignocellulosic data predicted TGA curves with exceptional accuracy (R2: 0.9996–0.9998).

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Cite This Study

Kordoghli et al. (2026) studied this question.

synapsesocial.com/papers/69bf3955c7b3c90b18b43ee1https://doi.org/10.3390/hydrogen7010043
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