Recovery Potential of Critical Rare Earth Elements from Coal Preparation Tailings: A Case Study of the Abayskaya Mine

Coal preparation tailings from the K18 seam of the Abayskaya mine were evaluated as a potential secondary source of critical rare earth elements (REEs). The study showed that REEs are predominantly associated with the mineral fraction of coal; therefore, during beneficiation, approximately 70% of their total content is transferred to flotation tailings. The concentrations of valuable elements in the tailings are as follows (g/t): Li—65; Sc—16; Y—17; Yb—2.5; V—135; and Ti—2293. These values significantly exceed the Clarke values and are comparable to those of some low-grade primary ores, indicating the potential of coal preparation wastes as a technogenic raw material for critical elements. To extract REEs from the resistant aluminosilicate matrix, a fluorine–ammonium sulfate thermochemical activation method was proposed. Using a probabilistic–deterministic experimental design approach, a mathematical model of the process was developed and optimal parameters were determined (400 °C, 120 min, (NH4)2SO4 consumption—140% relative to Al, NH4HF2 consumption—110% relative to Si), providing a feed liberation degree (by Al extraction) of up to 94%. Under optimal conditions, high leaching efficiencies of key elements were achieved: Sc (95%), Y (100%), Yb (100%), and Li (100%). The results demonstrate the significant potential of coal preparation tailings as a secondary resource of rare earth elements and confirm the efficiency of fluorine–ammonium sulfate technology for processing this type of technogenic waste.