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March 27, 2026International Journal of Chemistry and Technology1 citationsOpen Access

Valorization of Glass Wool Waste in Metakaolin-Based Geopolymers for Methylene Blue Adsorption

CKCansu KurtuluşAfyon Kocatepe University

Key Points

  • The research aims to evaluate the effectiveness of metakaolin and glass wool-based geopolymers in removing methylene blue from water.
  • Characterization using X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR)
  • Surface analysis with scanning electron microscopy (SEM-EDX)
  • BET analysis for specific surface area measurement
  • Evaluation of adsorption kinetics and regeneration experiments
  • The addition of glass wool increased surface roughness and porosity of geopolymers.
  • The maximum specific surface area reached 268.35 m2 g-1 with 100% glass wool.
  • The highest dye removal efficiency was noted in samples containing 100% glass wool and specific MK-GW combinations.
  • Adsorption followed a pseudo-second-order model indicating a chemisorption mechanism.
  • Regeneration experiments achieved over 80% capacity retention after two cycles.

Abstract

This study examines the efficacy of geopolymer composites derived from metakaolin (MK) and waste glass wool (GW) in the removal of methylene blue (MB) from aqueous solutions. For characterization, X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDX), and Brunauer-Emmett-Teller (BET) analysis were performed. The results showed that adding more GW made the surface rougher, more porous, and higher specific surface area. The sample made entirely of GW had a specific surface area of 268.35 m2 g-1. Structural analyses corroborated the emergence of calcium-aluminosilicate gel phases in GW formulations. Adsorption performance was closely related to the gel's surface area and composition. The 100 GW and 20-80 MK-GW samples had the highest removal efficiency. Kinetic studies showed that the pseudo-second-order model best described the process, indicating that chemisorption was the predominant mechanism. Regeneration experiments showed that stability was achieved, with more than 80% of the capacity remaining after two cycles. Overall, these results highlight GW-based geopolymers as sustainable and low-cost adsorbents for effective dye removal.

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Cite This Study

Cansu Kurtuluş (2026) studied this question.

synapsesocial.com/papers/69c620d515a0a509bde197e8https://doi.org/10.32571/ijct.1785921
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