Electrochemical Nitrogen Atom Insertion Enabled by a Manganese Complex

Minki Jeon; Pooja Kumari Jat; Juyoung Baek; Geon Kang; Jin Hee Kim; Isaac Choi

doi:10.1039/d6cc00221h

January 1, 2026Chemical CommunicationsOpen Access

Electrochemical Nitrogen Atom Insertion Enabled by a Manganese Complex

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Key Points

The aim is to explore a novel manganese-catalyzed method for nitrogen atom insertion into organic molecules.
Investigated mechanistic pathways involving manganese–azide intermediates.
Conducted electrochemical experiments to observe anodic oxidation processes.
Assessed a variety of functional groups for compatibility with the nitrogen insertion reaction.
Demonstrated successful nitrogen insertion into targeted organic substrates.
Identified manganese–azide intermediates as key players in the reaction mechanism.
Establishing the anodic oxidation pathway as critical for the reaction's efficiency.

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Implication

This research demonstrates nitrogen atom insertion in organic compounds, implying new synthetic pathways.

Abstract

Herein, we report a manganaelectrooxidative nitrogen atom insertion reaction. Detailed mechanistic studies reveal the crucial roles of manganese–azide intermediates and their anodic oxidation pathway, while a wide range of functional...

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Cite This Study

Jeon et al. (2026) studied this question.

synapsesocial.com/papers/69c772058bbfbc51511e22cd https://doi.org/10.1039/d6cc00221h

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Electrochemical Nitrogen Atom Insertion Enabled by a Manganese Complex

Key Points

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Implication

Abstract

Discussion

Cite This Study

Electrochemical Nitrogen Atom Insertion Enabled by a Manganese Complex

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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