PulseExploreJournal ClubDebatesTrendingResearchersJournals
Instagram
HomeExploreJournal ClubTrending
Synapse
⌘+K
Synapse
March 29, 2026Journal of Chemical Education3 citations

Ratiometric Luminescence Sensing of Perfluorooctanoic Acid with an Amino-Functionalized Lanthanide Metal–Organic Framework: An Integrated Undergraduate Laboratory Experiment

View Full Paper
XLXiao LiuWXWenya XiaZLZhiqiang Li

Key Points

  • The aim is to educate upper-division students on the synthesis and characterization of a lanthanide metal-organic framework and its application in sensing PFOA.
  • Synthesis of an amino-functionalized europium-based MOF via solvothermal synthesis.
  • Characterization using powder X-ray diffraction (PXRD) and Fourier-transform infrared (FT-IR) spectroscopy.
  • Detection of PFOA through ratiometric luminescence sensing.
  • Analysis of the sensing mechanism using zeta potential measurements.
  • Successful synthesis and characterization of the lanthanide MOF were achieved.
  • Quantitative detection of PFOA was demonstrated using ratiometric luminescence.
  • The experiment clarified the sensing mechanism through zeta potential and FT-IR measurements.

Abstract

A comprehensive laboratory experiment has been designed for upper-division undergraduate students, encompassing the synthesis and characterization of a lanthanide metal–organic framework (Ln-MOF) and its ratiometric luminescent sensing of perfluorooctanoic acid (PFOA), a persistent environmental pollutant. The students synthesized an amino-functionalized europium-based MOF via solvothermal synthesis. They then employed powder X-ray diffraction (PXRD), Fourier-transform infrared (FT-IR) spectroscopy, and luminescence spectroscopy to characterize the framework’s structure and investigate the “antenna effect”. Subsequently, they quantitatively and selectively detected PFOA using ratiometric luminescence sensing. Finally, the sensing mechanism was clarified through zeta potential and FT-IR measurements. This experiment not only enables students to apply and integrate the basic concepts from inorganic chemistry, analytical chemistry, and environmental chemistry but also provides them with a research-like experience, emphasizing instrumental operation training, collaborative data analysis, and the structure–property–application relationship of advanced functional materials.

Ask AI
Helpful
Bookmark
Share
View Full Paper

Cite This Study

Liu et al. (2026) studied this question.

synapsesocial.com/papers/69c8c247de0f0f753b39c89dhttps://doi.org/10.1021/acs.jchemed.6c00117
Ask AI
Helpful
Bookmark
Share
View Full Paper