Road transportation is a major contributor to global CO2 emissions, yet the influence of road geometry on vehicular emissions remains insufficiently quantified under real-world conditions. This study investigates the effects of horizontal and vertical alignments on CO2 emissions of a light-duty gasoline passenger vehicle using Portable Emissions Measurement System (PEMS) data collected along a 62.4 km highway section. Six geometric parameters longitudinal grade, cross slope, horizontal curve radius, horizontal curve length, vertical curve radius, and vertical curve length were analyzed in combination with second-by-second vehicle dynamics. The results indicate that transient CO2 emissions exhibit substantial variability, with instantaneous emission rates exceeding 7.0 g/s under high-load conditions. Longitudinal slope gradient shows the strongest linear association with emission rate (r = 0.63), while speed and acceleration exhibit weaker but statistically significant correlations (r = 0.21 and r = 0.28, respectively). Vehicle Specific Power (VSP), representing integrated tractive power demand, demonstrates stronger association with instantaneous CO2 emissions than individual kinematic variables. In contrast, cross slope and horizontal curvature parameters display minimal direct correlations under the tested highway conditions. A nonlinear polynomial regression model modestly improves explanatory performance relative to a linear formulation (R2 = 0.21 versus 0.15; RMSE approximately 56 g/km), although a substantial portion of variability remains unexplained, reflecting the complexity of transient real-world processes. Overall, vertical alignment and transient driving conditions dominate CO2 emission variability, while horizontal parameters play supplementary roles. These findings provide empirical evidence for refining emission models and highlight the importance of incorporating vertical alignment into sustainable roadway design and carbon reduction strategies.
Li et al. (2026) studied this question.