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March 29, 2026ACS Energy Letters2 citationsOpen Access

Metal–Hydrogen Batteries and Decoupled Electrolyzers: Converging Pathways for Hydrogen-Integrated Energy Storage

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LSLaura Sanchez-CupidoBABegoña AcebedoNONagore Ortiz-Vitoriano

Key Points

  • This work explores the integration of metal–hydrogen batteries and electrolyzers for energy storage, emphasizing shared challenges and opportunities.
  • Analyzed the redox chemistry of metal-hydrogen batteries and membrane-free electrolyzers.
  • Summarized benchmark metrics and identified shared scientific foundations.
  • Outlined design principles for mediators, electrodes, and interfaces.
  • Highlighted the convergence of distinct technologies through shared chemistries.
  • Emphasized best practices for standardized testing and reporting across platforms.
  • Outlined near-term research directions that support the integration of these technologies.

Abstract

Electrochemical energy storage and hydrogen conversion have historically been developed as separate technologies, yet their chemistries and engineering challenges overlap profoundly. Metal–hydrogen (M–H2) batteries and redox-mediated, membrane-free electrolyzers both rely on reversible hydrogen redox chemistry in aqueous or hybrid electrolytes. This Perspective examines how these systems, once considered distinct, are converging at the level of redox chemistry, materials challenges, and benchmarking needs while retaining distinct architectures and engineering constraints for dispatchable, long-duration energy storage. It summarizes benchmark metrics for each platform, identifies shared scientific foundations, and outlines design principles for mediators, electrodes, and interfaces. Emphasis is placed on best practices for standardized testing and reporting, cross-disciplinary benchmarking, and near-term research directions. By viewing M–H2 batteries and decoupled electrolyzers as complementary elements rather than competitors, it becomes possible to envision a cohesive hydrogen-integrated energy infrastructure spanning seconds-to-seasons storage.

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Cite This Study

Sanchez-Cupido et al. (2026) studied this question.

synapsesocial.com/papers/69c8c35cde0f0f753b39e182https://doi.org/10.1021/acsenergylett.5c03575
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