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Statistical analysis reveals the equilibrium relation of wustite with gas phases, indicating thermodynamic properties in steel-making.
Under the assumption that wustite is an ionic crystal containing the lattice imperfections such as the vacant lattice points formed by the removal of Fe^<++> ions and the accompanying electron deficits in the form of Fe^<+++> ion distributing among the Fe^<++> ion lattice points, the partition function and free energy of such a crystal were calculated, and the formula showing the equilibrium relation between the gas phase and wustite was derived. This formula is in good agreement with the detailed experimental results.
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TAKEUCHI et al. (1952) studied this question.
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