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April 3, 2026Results in Chemistry0 citationsOpen Access

Synthesis and characterization of cerium bismuth oxide nanocomposite: Enhanced photocatalytic degradation of crystal violet dye

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DGDeepan Raj GunasekaranSVS P Vijayachamundeeswari

Key Points

  • The aim is to synthesize and characterize cerium bismuth oxide nanoparticles for enhanced photocatalytic degradation of crystal violet dye.
  • Synthesized cerium bismuth oxide nanoparticles using the precipitation method.
  • Characterized nanoparticles using techniques like X-ray diffraction (XRD), UV-visible spectroscopy, FTIR, and scanning electron microscopy (SEM).
  • Measured structural properties, optical bandgap, and surface morphology.
  • Crystallite sizes were identified as 43 nm for bismuth oxide, 23 nm for cerium oxide, 19 nm for cerium bismuth oxide (1:1), and 27 nm for (2:1).
  • Bandgap energies were found to be 2.9 eV for Bi2O3, 3.2 eV for CeO2, 2.4 eV for CBO (1:1), and 2.6 eV for CBO (2:1).
  • Photocatalytic activity showed significant dye degradation under sunlight, as supported by total organic carbon (TOC) removal data.

Abstract

Cerium Bismuth Oxide nanoparticles were synthesized through chemical synthesis employing the precipitation method. Bismuth (Bi) and cerium (Ce), bifunctional materials effectively remove harmful chemicals from water through photocatalytic degradation. The several attributes of the nanoparticles were tested using different characterization techniques. The powder X-ray diffraction (XRD) technique was used to analyse the structural properties of the materials, and the crystallite size was found to be 43 nm for bismuth oxide (Bi 2 O 3 ), 23 nm for Cerium Oxide(CeO 2 ), 19 nm for Cerium Bismuth Oxide (CBO) (1:1), and 27 nm for CBO (2:1) ratio. The optical properties of the synthesized nanoparticles were characterized using UV–visible spectroscopy. The bandgap was plotted using Kubelka–Munk plots and found to be 2.9 eV for Bi 2 O 3 , 3.2 eV for CeO 2 , 2.4 eV for CBO (1:1), and 2.6 eV for CBO (2:1), respectively. The functional groups of the nanomaterials were studied using Fourier transform infrared (FTIR) spectroscopy. The surface morphology of synthesized nanoparticles was analysed via scanning electron microscopy (SEM). Cerium Bismuth Oxide nanoparticles were synthesized through chemical synthesis employing the precipitation method. Photocatalytic testing under sunlight shows higher activity for the nanocomposite, supported by TOC removal data.

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Cite This Study

Gunasekaran et al. (2026) studied this question.

synapsesocial.com/papers/69cf5ced5a333a821460a764https://doi.org/10.1016/j.rechem.2026.103286
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