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April 3, 2026Discover Catalysis.2 citationsOpen Access

Biodiesel synthesis using waste cooking oil via transesterification over heterogeneous inorganic perovskites catalysts: a study of co-solvent effect and surface thermodynamics

KBKetshepile BaabuaRPRapelang PatalaHLHui Li

Key Points

  • The aim is to explore the impact of co-solvent on biodiesel synthesis from waste cooking oil using heterogeneous perovskite catalysts.
  • Conducted transesterification of waste cooking oil using LaMoO3 catalyst.
  • Evaluated the effect of hexane as a solvent and co-solvent.
  • Analyzed the thermodynamics of the reaction near methanol's boiling point.
  • Achieved 88.7% conversion rate of triglycerides to fatty acid-methyl esters with hexane as a co-solvent.
  • Identified that co-solvent enhances solubility of reacting substances.
  • Revealed thermodynamic principles govern the transesterification process.

Abstract

Herein we report on the transesterification of waste cooking oil (WCO) to biodiesel as an alternative route to the attainment of green biodiesel over LaMoO3 catalyst. Preliminary results suggest that hexane, as a solvent and co-solvent plays a significant role in enhancing the solubility of the reacting species and elevating the triglycerides transesterification with methanol to fatty acid-methyl esters (FAME). At the same reaction condition, the addition of hexane as a co-solvent enhances the triglyceride’s conversion to 88.7%. Furthermore, the thermodynamic interpretation of the production of FAME revealed that the transesterification of waste cooking oil is governed by the surface thermodynamics near the methanol boiling point.

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Cite This Study

Baabua et al. (2026) studied this question.

synapsesocial.com/papers/69cf5dc55a333a821460bc2bhttps://doi.org/10.1007/s44344-026-00037-8
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