SLi 4 X 3 - (X = Cl, Br, I)：fan-shaped superhalogen anions featuring planar tetracoordinate sulfur

Ting Zhang; Yaxuan Cheng; Jin‐Chang Guo

doi:10.1039/d6cp00920d

January 1, 2026Physical Chemistry Chemical Physics

SLi 4 X 3 - (X = Cl, Br, I)：fan-shaped superhalogen anions featuring planar tetracoordinate sulfur

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Key Points

The aim is to design and explore the properties of planar tetracoordinate sulfur anions SLi 4 X 3 - (X = Cl, Br, I).
Utilized a strategy of partially eliminating after isoelectronic replacing
Designed mono-anionic clusters featuring varying halides
Analyzed structural and electronic properties of the created anions
Successfully designed the first planar tetracoordinate sulfur anions
Demonstrated unique superhalogen characteristics
Highlighted potential applications in new chemical systems

Implication

Novel planar tetracoordinate sulfur clusters exhibit superhalogen properties, indicating new chemical potential.

Abstract

The first planar tetracoordinate sulfur (ptS) SLi 4 X 3 - (X = Cl, Br, I) mono-anionic clusters have been designed by using the "partially eliminating after isoelectonicreplacing" strategy, inspired...

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Cite This Study

Zhang et al. (2026) studied this question.

synapsesocial.com/papers/69d0aff2659487ece0fa6110 https://doi.org/10.1039/d6cp00920d

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SLi 4 X 3 - (X = Cl, Br, I)：fan-shaped superhalogen anions featuring planar tetracoordinate sulfur

Key Points

Implication

Abstract

Discussion

Cite This Study

SLi 4 X 3 - (X = Cl, Br, I)：fan-shaped superhalogen anions featuring planar tetracoordinate sulfur

Key Points

Implication

Abstract

Discussion

Cite This Study

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