The aim is to design and explore the properties of planar tetracoordinate sulfur anions SLi 4 X 3 - (X = Cl, Br, I).
Utilized a strategy of partially eliminating after isoelectronic replacing
Designed mono-anionic clusters featuring varying halides
Analyzed structural and electronic properties of the created anions
Successfully designed the first planar tetracoordinate sulfur anions
Demonstrated unique superhalogen characteristics
Highlighted potential applications in new chemical systems
Abstract
The first planar tetracoordinate sulfur (ptS) SLi 4 X 3 - (X = Cl, Br, I) mono-anionic clusters have been designed by using the "partially eliminating after isoelectonicreplacing" strategy, inspired...