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April 5, 2026Frontiers in Energy Research3 citationsOpen Access

Biodiesel synthesis from Blighia sapida seed oil: comparative modelling via RSM and ANFIS–PSO hybrid optimization

OOOyetola OgunkunleMOMicheal O. Olusanya

Key Points

  • The research aims to optimize the biodiesel production process from Blighia sapida seed oil using advanced modeling techniques.
  • Optimized transesterification via a two-step esterification and transesterification process.
  • Explored various process variables: methanol-to-oil ratio, catalyst concentration, reaction temperature, and time.
  • Utilized Response Surface Methodology and ANFIS–PSO for modeling and optimization.
  • Evaluated model performance using R2, RMSE, and MAE metrics.
  • ANFIS–PSO achieved R2 = 0.9997, outperforming RSM's R2 = 0.9896.
  • Optimal conditions yielded 96.21% biodiesel from B. sapida seed oil.
  • Biodiesel satisfied international standards for viscosity, flash point, density, acid value, and cetane number.

Abstract

The depletion of fossil fuels and growing environmental concerns necessitate the development of renewable biofuels. Blighia sapida seed oil, an inedible and underutilized resource, presents a viable option for biodiesel production. This study optimized its transesterification process using advanced modelling to improve yield and fuel quality. A two-step esterification–transesterification approach was used, with process variables, methanol-to-oil molar ratio (6:1–12:1), catalyst concentration (0.5–1.5 wt%), reaction temperature (50°C–70 °C), and time (30–90 min), optimized via Response Surface Methodology (RSM) and Adaptive Neuro-Fuzzy Inference System integrated with Particle Swarm Optimization (ANFIS–PSO). Model performance was evaluated using R 2 , RMSE, and MAE. ANFIS–PSO outperformed RSM with R 2 = 0.9997, RMSE = 0.0925, and MAE = 0.0721, compared to RSM’s R 2 = 0.9896, RMSE = 0.6384, and MAE = 0.4162. Optimal ANFIS–PSO conditions, methanol-to-oil ratio of 9.8:1, catalyst concentration of 1.2 wt%, temperature of 62 °C, and reaction time of 78 min, yielded 96.21% biodiesel. The biodiesel met international standards: kinematic viscosity (3.38 mm 2 /s), flash point (167 °C), density (0.8765 g/cm 3 ), acid value (1.178 mg KOH/g), and cetane number (58.06). These findings validate B. sapida as a promising biodiesel feedstock and position ANFIS–PSO as a superior modelling tool for scalable biofuel production from non-edible sources.

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Cite This Study

Ogunkunle et al. (2026) studied this question.

synapsesocial.com/papers/69d1fb20a79560c99a0a1827https://doi.org/10.3389/fenrg.2026.1783127
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