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April 8, 2026Journal of Applied Polymer Science2 citations

Preparation of UV Aging‐Resistant SBS Polymer‐Modified Asphalt and Its Underlying Aging Resistance Mechanism

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DZDerun ZhangJTJinbiao TangYGYichen Guo

Key Points

  • The aim is to enhance UV aging resistance in SBS-modified asphalt and understand the underlying mechanisms.
  • Developed a novel SBS-modified asphalt with UV absorbers and a light stabilizer.
  • Conducted tests using dynamic shear rheometer (DSR) and bending beam rheometer (BBR).
  • Examined microscopic structures via atomic force microscopy (AFM) and infrared spectroscopy (FTIR).
  • Investigated the synergistic effect on aging resistance through ultraviolet-visible (UV-Vis) spectroscopy.
  • UV absorbers and light stabilizer significantly improved UV aging resistance.
  • Identified dual mechanisms of UV aging involving oxidative aging and SBS polymer degradation.
  • Absorbers convert UV energy to thermal energy, reducing free radical generation.
  • Light stabilizer scavenges free radicals and inhibits aging reactions.

Abstract

ABSTRACT To enhance the UV aging resistance of SBS‐modified asphalt and elucidate the underlying UV aging resistance mechanisms, this study developed a novel UV aging‐resistant SBS‐modified asphalt by incorporating UV absorbers and a light stabilizer. The dual mechanisms of UV aging in SBS‐modified asphalt were investigated from both macroscopic properties and microscopic structures through dynamic shear rheometer (DSR) test, bending beam rheometer (BBR) test, and Fourier transform infrared (FTIR) spectroscopy test. Furthermore, the synergistic effect of the UV absorbers and light stabilizer was examined via atomic force microscopy (AFM) and ultraviolet–visible (UV–Vis) spectroscopy. The test results demonstrate that the UV absorbers and light stabilizer significantly improve the UV aging resistance of SBS‐modified asphalt. The SBS‐modified asphalt has dual UV aging mechanisms, which involves both the oxidative aging of the base asphalt and the degradation of SBS polymer chains. The UV absorbers act by absorbing UV energy and converting it into thermal energy, thereby reducing the generation of free radicals in the asphalt matrix and suppressing the oxidation of asphaltene molecules. The light stabilizer further terminates the aging chain reaction by scavenging free radicals and decomposing hydroperoxides, thus inhibiting the aging and performance degradation of SBS‐modified asphalt.

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Cite This Study

Zhang et al. (2026) studied this question.

synapsesocial.com/papers/69d5f14b74eaea4b11a7ad6chttps://doi.org/10.1002/app.70754
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