The first hypercoordinate silicon-bridged [1]ferrocenophane shows a pronounced Si−N interaction, a pseudo-trigonal-bipyramidal geometry at the bridging silicon atom, an elongated Si−Cp bond trans to the amino group, and an unusually long Fe−Si distance in comparison to the tetracoordinate analogues.
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Jäkle et al. (2000) studied this question.
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