A study was conducted to demonstrate the use of calixarenes in metal-based catalysis. The study focused on rare earth metal-containing species,including neodymium to demonstrate the use of calixarenes in metal-based catalysis. It was found that the ability to make calixarenes water-soluble allowed them to be used as catalysts in aqueous media, demonstrating that calixarene-based systems were employed as homo- or heterogeneous catalysts. It was demonstrated that the availability of chiral calixarenes offered significant advantages for calixarene-based catalysis of metals. It was also demonstrated that the characteristics and availability of calixarenes made them potentially environmentally friendly for catalytic applications in academic research activities and industrial processes.
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Homden et al. (2008) studied this question.
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