Characterizing multifaceted environmental risks of oil and gas well leakage through soil and well methane and hydrogen sulfide emissions

Oil and gas wells (OGWs) can lead to soil and well emissions of methane (CH4), a potent greenhouse gas, and hydrogen sulfide (H2S), a highly toxic gas, both of which reduce air quality and can cause explosions when emitted into confined spaces. Developments have been occurring over OGWs, posing health and safety risks. However, to our knowledge, previous studies have not conjunctively analyzed well and soil emissions while considering development on or near OGWs. In this paper, we characterize 343 CH4 and H2S emission rate measurements from 67 non-producing (abandoned) and 35 producing (active) OGWs, including 205 measurements from soils surrounding 81 OGWs in Ontario and Quebec. We also provide the first emission rate estimates from an abandoned water and OGW-linked explosion and map OGWs in urban and built-up areas in Ontario and Quebec. We estimate the explosion-linked emissions to be 3,000 g CH4/hour and 7 g H2S/hour. Moreover, we find that 7,264 and 161 OGWs in Ontario and Quebec, respectively, are in urban and built-up areas, with 94% of these wells being abandoned. For the 102 wells we measured, of which 9.7% had H2S detections, we find OGW emission rate ranges of -16 to 47,000 mg CH4/hour and 0.001 to 3,300 mg H2S/hour. Although soil CH4 emissions at a 1-m distance from the wells are most correlated with well emissions, the highest soil emission rate was observed at a 3-m distance, indicating the potential for OGW-related emissions into buildings to occur away from the well. Overall, our multi-faceted measurement dataset provides a basis for conjunctive analysis of the broad range of environmental risks of OGWs to climate, indoor and outdoor air quality, and explosions.