Simple and Continuous Fabrication of Self-Propelled Micromotors with Photocatalytic Metal–Organic Frameworks for Enhanced Synergistic Environmental Remediation

This work reports on a simple and general strategy for continuous fabrication of self-propelled micromotors with photocatalytic metal-organic frameworks (MOFs) for enhanced synergistic degradation of organic contaminants. With emulsion microdroplets from microfluidics as templates, uniform porous micromotors decorated with Fe₃O₄@Ag nanoparticles (Fe₃O₄@AgNPs) at the bottom and zeolitic imidazolate framework-8@ZnO nanoparticles (ZIF-8@ZnONPs) on the surface can be synthesized. The spatial location of ZIF-8@ZnONPs and Fe₃O₄@AgNPs in micromotors is accurately controlled in one step via their directional migration in the confined microspace of emulsion droplets driven by interfacial energy and magnetic field. The nanoengines Fe₃O₄@AgNPs enable asymmetric decomposition of H₂O₂ for bubble-propelled motion and easy magnetic recycling of the micromotor. The porous structures of micromotors provide a large surface area, benefiting decoration of Fe₃O₄@AgNPs and their contact with H₂O₂ for promoting bubble generation and reduced micromotor weight for promoting bubble-propelled motion. The nanophotocatalysts ZIF-8@ZnONPs allow enrichment of organic contaminant molecules via adsorption for efficient photocatalytic degradation. With synergistic coupling of the photocatalysis of ZIF-8@ZnONPs and advanced oxidation of the H₂O₂/UV system, the micromotors with bubble-propelled motion for improved mixing can achieve enhanced degradation of organic contaminants via dual synergistic degradation mechanisms. As highlighted by degradation of rhodamine B, the micromotors exhibit the highest degradation performance as compared to control groups with a single degradation mechanism and with dual degradation mechanisms but without self-propelled motion. This simple fabrication strategy is general and can be flexibly extended to other MOF materials, which may open up new avenues for developing advanced MOF-integrated micromotors for myriad applications.