Answers are grounded in this paper and cite their sources.
We have synthesized a new homoconjugated donor–acceptor (D–A) system featuring a rigid planar carbon-bridged oligo(p-phenylenevinylene) that shows efficient intramolecular charge separation (CS, 98%). The charge recombination rate is 100-times slower than that of CS, and located in the Marcus inverted region. The electronic coupling was estimated to be 1.0 × 103 cm−1, which is one of the largest values among reported D–A interactions.
No takes yet. Share an insight, caveat, or question.
Sukegawa et al. (2014) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: