We investigated tradeoff characteristics between resistivity and reliability for scaled-down Cu-based interconnects. A unique resistivity-measurement technique is proposed to detect influences due to impurity doping. Using this technique, we investigated the impacts of the impurity doping on three types of copper interconnects - cobalt-tungsten-phosphorous (CoWP) metal-cap interconnects, plasma-enhanced chemical-vapor-deposition self-aligned barrier interconnects, and CuAl alloy interconnects - and clarified the tradeoffs between the resistivity and the reliability. We found that the metal-cap interconnect shows not only high reliability but also outstanding efficiency with regard to the suppression of resistance increase due to impurity doping.
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Yokogawa et al. (2008) studied this question.
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