What question did this study set out to answer?

To review the synthesis, theoretical foundations, and functional applications of metal-organic frameworks featuring analytically verified open metal sites.

January 1, 2020Chemical Society Reviews

Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

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To review the synthesis, theoretical foundations, and functional applications of metal-organic frameworks featuring analytically verified open metal sites.
Survey of synthetic strategies used to generate vacant Lewis acid coordination sites on framework metal ions and cluster nodes.
Evaluation of analytical techniques required to confirm and validate the presence of open coordination sites.
Assessment of theoretical models of host-guest interactions alongside practical application performance metrics.
Identifies reproducible synthetic pathways for generating vacant coordination sites while emphasizing the critical necessity of definitive analytical verification.
Details how coordinatively unsaturated sites enhance binding affinities in host-guest interactions to advance selective gas separation, chemical sensing, and catalysis.

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Implication

Comprehensive review demonstrates preparation strategies and host-guest interaction effects of open metal sites in metal-organic frameworks, highlighting targeted functional materials design.

Cite This Study

Kökçam-Demir et al. (2020) studied this question.

synapsesocial.com/papers/69d737d0aa68b335b4f30843 https://doi.org/10.1039/c9cs00609e

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Implication

Comprehensive review demonstrates preparation strategies and host-guest interaction effects of open metal sites in metal-organic frameworks, highlighting targeted functional materials design.

Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

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Discussion

Implication

Cite This Study

Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Key Points

Discussion

Implication

Cite This Study

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