Soil Acidification by Fertilizers and Longevity of Lime Applications in the Peace River Region

Acidification of two soils was measured in an experiment in which fertilizer and CaCO 3 treatments were applied in various combinations. The highest rate of fertilizer used, which included N at 139 kg/ha, decreased the pH in 4–5 yr in unlimed Donnelly (Gray Luvisol) and Josephine (Eluviated Gleysol) soils by 0.43 and 0.18 units, respectively. The fertilizer increased the soluble Al content in both soils. Yields of barley (Hordeum vulgare L.) were greatly increased by the fertilizer and lime treatments. However, by the fourth crop on the Josephine soil, fertilizer failed to give a yield increase in the absence of lime; this was apparently due to declining soil pH and increasing soluble Al. In another experiment, loss of lime was measured over an 8-yr period in six soils that had been limed with Ca(OH) 2 to pH 6.5–7.0. The average loss of lime from the soils was equivalent to 495 kg of CaCO 3 /ha annually. This was accompanied by a decline in pH of 0.48 unit in the 8 yr. Liming caused substantial increases to subsoil pH for three of the soils. Despite the decline in surface soil pH, increases in yields of barley from liming were sustained over the 8-yr period. The implication of these findings to soil fertility practices in the Peace River region are discussed.