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We develop relative kinetics for heterogeneous oxidation of multi‐component organic aerosols. Common accommodation, diffusion, and deposition terms cancel in this formulation, and rate constants may be determined for many compounds simultaneously within an aerosol with a realistic composition. Finally, cross‐phase relative rate constants with a gas‐phase reference compound and a condensed‐phase target compound provide effective rate constants for use in atmospheric models.
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Donahue et al. (2005) studied this question.
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