Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B₁₂O₁₆F₄(OH)₄] Clusters

Polarization modulation of deep-UV light is of significance to current technologies, and to this end, the birefringent crystal has emerged as an invaluable material as it allows for effective light modulation. Herein, a double-modification strategy driven by F and OH anions that makes double effects towards the critical property enhancement of deep-UV birefringent crystals is proposed. This leads to a new hydroxyborate (NH₄ )₄ [B₁₂ O₁₆ F₄ (OH)₄ ] with giant cluster as a deep-UV birefringent crystal with large birefringence (Δnexp. =0.12@546.1 nm). This birefringence is a record among inorganic hydroxyborates with experimentally measured birefringence. Structural analysis shows that the near-plane arrangement of [B₁₂ O₁₆ F₄ (OH)₄ ] cluster is responsible for the large optical anisotropy. Theoretical calculations indicate that its π-conjugated [BO₃ ] and [BO₂ OH] units are the main source of this large optical anisotropy.