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Abstract In this work all‐inorganic perovskite CsPbIBr 2 are doped with Mn to compensate their shortcomings in band structure for the application of perovskite solar cells (PSCs). The novel Mn‐doped all‐inorganic perovskites, CsPb 1− x Mn x I 1+2 x Br 2−2 x , are prepared in ambient atmosphere. As the concentration of Mn 2+ ions increases, the bandgaps of CsPb 1− x Mn x I 1+2 x Br 2−2 x decrease from 1.89 to 1.75 eV. Additionally, when the concentration of Mn dopants is appropriate, this novel Mn‐doped all‐inorganic perovskite film shows better crystallinity and morphology than its undoped counterpart. These advantages alleviate the energy loss in hole transfer and facilitate the charge‐transfer in perovskites, therefore, PSCs based on these novel CsPb 1− x Mn x I 1+2 x Br 2−2 x perovskite films display better photovoltaic performance than the undoped CsPbIBr 2 perovskite films. The reference CsPbIBr 2 cell reaches a power conversion efficiency (PCE) of 6.14%, comparable with the previous reports. The CsPb 1− x Mn x I 1+2 x Br 2−2 x cells reach the highest PCE of 7.36% (when x = 0.005), an increase of 19.9% in PCE. Furthermore, the encapsulated CsPb 0.995 Mn 0.005 I 1.01 Br 1.99 cells exhibit good stability in ambient atmosphere. The storage stability measurements on the encapsulated PSCs reveal that PCE is dropped by only 8% of the initial value after >300 h in ambient. Such improved efficiency and stability are achieved using low‐cost carbon electrodes (without expensive hole transport materials and Au electrodes).
Liang et al. (Thu,) studied this question.