January 1, 2016Open Access

Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film

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Abstract

Here, we demonstrate a new strategy for cooperative catalysis and proton abstraction via the incorporation of independent species competent in the desired reactivity into a metal–organic framework (MOF) thin film.

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Authors

Pavel M. Usov

Tokyo Institute of Technology

Spencer R. Ahrenholtz

Virginia Tech

William A. Maza

United States Naval Research Laboratory

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Journal of Materials Chemistry A

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Virginia Tech

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Usov et al. (Fri,) studied this question.

synapsesocial.com/papers/69d8a875ce048d2571bed876 — DOI: https://doi.org/10.1039/c6ta05877a

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A Water‐Stable Porphyrin‐Based Metal–Organic Framework Active for Visible‐Light Photocatalysis· 2012 · 185 citations
Recent developments in metal–metalloporphyrin frameworks· 2015 · 58 citations

Also consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

Introduction: Solar Energy Conversion· 2015 · 128 citations
Mechanism of Catalytic Oxygenation of Alkanes by Halogenated Iron Porphyrins· 1994 · 322 citations
Electrochemical Reduction of CO<sub>2</sub> to CO Catalyzed by a Bimetallic Palladium Complex· 2006 · 145 citations
A Water‐Stable Porphyrin‐Based Metal–Organic Framework Active for Visible‐Light Photocatalysis· 2012 · 185 citations
Recent developments in metal–metalloporphyrin frameworks· 2015 · 58 citations

Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film

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