Stiffness Enhancement, Anti-Aging, and Self-Forming Holes in Polycarbonate/Acrylonitrile-Styrene-Acrylic by the Core-Shell Structure of Acrylic Resin

Currently, polycarbonate/acrylonitrile-styrene-acrylic (PC/ASA) is used mainly in the automotive, outdoor electronic equipment, sports equipment, and medical care fields, but its use is limited by its poor impact resistance and aging characteristics. This study investigates the preparation of polycarbonate/acrylonitrile-styrene-acrylic/acrylic resin (PC/ASA/ACE) via melt blending. We observed that the addition of acrylic resin (ACE) enhanced the impact strength (up to 14.1%) and abrasion resistance (up to 35.7%) of the blends compared to PC/ASA. The microstructure of the copolymer was observed by scanning electron microscopy and laser scanning confocal microscopy. They were found to have a self-forming hole phenomenon, which is more favorable for potential PC/ASA applications. Furthermore, ACE addition effectively enhances the copolymer toughness and wear properties but slightly reduces their hardness, tensile strength, and melt flow rate, improving their suitability for use in applications such as aircraft windshields. After 80 cycles of aging, the PC/ASA/ACE also outperformed the impact strength of the unaged PC/ASA. ACE addition to PC/ASA can create materials with better impact and aging resistance.