Electrode–Electrolyte Interfacial Chemistry Modulation for Ultra‐High Rate Sodium‐Ion Batteries

Sodium-ion batteries capable of operating at rate and temperature extremes are highly desirable, but elusive due to the dynamics and thermodynamics limitations. Herein, a strategy of electrode-electrolyte interfacial chemistry modulation is proposed. The commercial hard carbon demonstrates superior rate performance with 212 mAh g⁻¹ at an ultra-high current density of 5 A g⁻¹ in the electrolyte with weak ion solvation/desolvation, which is much higher than those in common electrolytes (nearly no capacity in carbonate-based electrolytes). Even at -20 °C, a high capacity of 175 mAh g⁻¹ (74 % of its room-temperature capacity) can be maintained at 2 A g⁻¹ . Such an electrode retains 90 % of its initial capacity after 1000 cycles. As proven, weak ion solvation/desolvation of tetrahydrofuran greatly facilitates fast-ion diffusion at the SEI/electrolyte interface and homogeneous SEI with well-distributed NaF and organic components ensures fast Na⁺ diffusion through the SEI layer and a stable interface.