Persistent carbon-centered radicals

D. Griller; K. U. Ingold

doi:10.1021/ar50097a003

January 1, 1976Accounts of Chemical Research

Persistent carbon-centered radicals

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Key Points

Synthesize current understanding of the structural features, electronic configurations, and stability mechanisms that govern persistent carbon-centered radicals.
Systematic evaluation of steric shielding and thermodynamic stabilization mechanisms in open-shell organic chemistry.
Analysis of electron paramagnetic resonance characterization techniques and kinetic stability profiles across diverse radical classes.
Steric congestion around the radical carbon center substantially suppresses dimerization and secondary degradation pathways.
Extensive resonance delocalization across conjugated aromatic frameworks lowers radical ground-state free energy to sustain chemical persistence.

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Implication

Narrative review reveals structural and electronic stabilization pathways in persistent carbon-centered radicals, highlighting design strategies for functional open-shell materials.

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Griller et al. (1976) studied this question.

synapsesocial.com/papers/69d914ed9402b8412aa3c059 https://doi.org/10.1021/ar50097a003

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Persistent carbon-centered radicals

Key Points

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Implication

Abstract

Discussion

Cite This Study

Persistent carbon-centered radicals

Key Points

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Implication

Abstract

Discussion

Cite This Study

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