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A metal‐free visible‐light‐promoted regioselective trifluoromethylselenolation of electron‐rich heteroarenes has been developed using C–H functionalization. This eco‐friendly, atom‐economical, and easy‐to‐operate protocol provides direct access to a wide range of functionalized SeCF 3 ‐containing heteroarenes in high yields, and is amenable to continuous flow techniques. A radical mechanism was supported by EPR experiments.
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Zordo‐Banliat et al. (2019) studied this question.
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