Defect microdynamics in minerals and solid‐state mechanisms of seismic wave attenuation and velocity dispersion in the mantle

The propagation of seismic waves in the Earth's mantle can be significantly affected by relaxation processes, causing attenuation and velocity dispersion (reduction). This paper reviews the solid‐state mechanisms of relaxation processes based on the theory of defect microdynamics in solids together with some experimental observations on defects in minerals (particularly in olivine). For a given mechanism to have a significant effect on seismic wave propagation, both the density and the mobility of the defects must be in an appropriate range. The examination of the densities (and geometry) and mobilities of defects in olivine shows that dislocation and/or grain boundary mechanisms can have a significant effect on seismic wave propagation, although wide distributions of geometrical factors (such as spacing of pinning points) and of mobilities are required to explain all available data. Point defect mechanisms, however, are unlikely to be important because their densities are too small and/or their mobilities are too large. Since the dislocation density and/or grain size are determined in most cases by the long‐term tectonic stress, seismic wave attenuation and velocity dispersion (reduction) involving these defects are likely to depend on the magnitude of the tectonic stress as well as the temperature. Theoretical considerations suggest a wide range of dependence of seismic wave attentuation (and velocity dispersion) on the long‐term tectonic stress. This is particularly the case for dislocation mechanisms and warrants careful experimental investigation. Dislocations and/or grain boundaries cause anelastic behavior (relaxation peaks) when they are pinned or blocked at some points. Pinning or blocking becomes ineffective at high temperatures and/or low frequencies, causing a transition to viscoelastic behavior. Both laboratory and seismological observations of internal friction are dominated by the “high‐temperature background” where internal friction increases monotonically with temperature, which can be interpreted as a gradual transition to viscoelastic behavior or to a wide distribution of relaxation times. However, in most experimental studies to date, the dislocation densities or the grain sizes were not well controlled, making it difficult to identify the attenuation mechanisms and preventing any quantitative applications to Earth. The need for better characterization of defect microstructures in experimental specimens is emphasized.