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A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm(2) V(-1) s(-1) , respectively.
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Qin et al. (2014) studied this question.
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