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November 1, 1953Physical Review1,908 citations

A Collective Description of Electron Interactions: III. Coulomb Interactions in a Degenerate Electron Gas

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DBDavid BöhmUniversity of LondonDPDavid PinesUniversity of Copenhagen

Key Points

  • This research aims to analyze the interactions of electrons in a dense electron gas using quantum mechanics.
  • Canonical transformations applied to the Hamiltonian for individual electrons with Coulomb interactions.
  • Description of long-range interactions in terms of collective fields representing plasma oscillations.
  • Elimination of field-particle interactions to approximate independent collective fields.
  • The Hamiltonian accurately represents electrons interacting via screened Coulomb forces with a range linked to inter-electronic distances.
  • The study identifies conditions that inhibit long wavelength electronic density fluctuations.
  • The analysis highlights a reduced number of electronic degrees of freedom through the described transformations.

Abstract

The behavior of the electrons in a dense electron gas is analyzed quantum-mechanically by a series of canonical transformations. The usual Hamiltonian corresponding to a system of individual electrons with Coulomb interactions is first re-expressed in such a way that the long-range part of the Coulomb interactions between the electrons is described in terms of collective fields, representing organized "plasma" oscillation of the system as a whole. The Hamiltonian then describes these collective fields plus a set of individual electrons which interact with the collective fields and with one another via short-range screened Coulomb interactions. There is, in addition, a set of subsidiary conditions on the system wave function which relate the field and particle variables. The field-particle interaction is eliminated to a high degree of approximation by a further canonical transformation to a new representation in which the Hamiltonian describes independent collective fields, with n^' degrees of freedom, plus the system of electrons interacting via screened Coulomb forces with a range of the order of the inter electronic distance. The new subsidiary conditions act only on the electronic wave functions; they strongly inhibit long wavelength electronic density fluctuations and act to reduce the number of individual electronic degrees of freedom by n^'. The general properties of this system are discussed, and the methods and results obtained are related to the classical density fluctuation approach and Tomonaga's one-dimensional treatment of the degenerate Fermi gas.

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Cite This Study

Böhm et al. (1953) studied this question.

synapsesocial.com/papers/69d9eb0e0d540cafc5838037https://doi.org/10.1103/physrev.92.609
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