Ti₃C₂Tx/MoS₂ Self‐Rolling Rod‐Based Foam Boosts Interfacial Polarization for Electromagnetic Wave Absorption

Heterogeneous interface design to boost interfacial polarization has become a feasible way to realize high electromagnetic wave absorbing (EMA) performance of dielectric materials. However, interfacial polarization in simple structures such as particles, rods, and flakes is weak and usually plays a secondary role. In order to enhance the interfacial polarization and simultaneously reduce the electronic conductivity to avoid reflection of electromagnetic wave, a more rational geometric structure for dielectric materials is desired. Herein, a Ti₃ C₂ Tx /MoS₂ self-rolling rod-based foam is proposed to realize excellent interfacial polarization and achieve high EMA performance at ultralow density. Different surface tensions of Ti₃ C₂ Tx and ammonium tetrathiomolybdate are utilized to induce the self-rolling of Ti₃ C₂ Tx sheets. The rods with a high aspect ratio not only remarkably improve the polarization loss but also are beneficial to the construction of Ti₃ C₂ Tx /MoS₂ foam, leading to enhanced EMA capability. As a result, the effective absorption bandwidth of Ti₃ C₂ Tx /MoS₂ foam covers the whole X band (8.2-12.4 GHz) with a density of only 0.009 g cm⁻³ , at a thickness of 3.3 mm. The advantages of rod structures are verified through simulations in the CST microwave studio. This work inspires the rational geometric design of micro/nanostructures for new-generation EMA materials.