Multifunctional Latex/Polytetrafluoroethylene-Based Triboelectric Nanogenerator for Self-Powered Organ-like MXene/Metal–Organic Framework-Derived CuO Nanohybrid Ammonia Sensor

Self-powered sensors are crucial in the field of wearable devices and the Internet of Things (IoT). In this paper, an organ-like Ti₃C₂Tx MXene/metal-organic framework-derived copper oxide (CuO) gas sensor was powered by a triboelectric nanogenerator (TENG) based on latex and polytetrafluoroethylene for the detection of ammonia (NH₃) at room temperature. The peak-to-peak value of open-circuit voltage and short-circuit current generated by the prepared TENG can reach up to 810 V and 34 μA, respectively. The TENG can support a maximum peak power density of 10.84 W·m⁻² and light at least 480 LEDs. Moreover, a flexible TENG under a single-electrode working mode was demonstrated for human movement stimulation, which exhibits great potential in wearable devices. The self-powered NH₃ sensor driven by TENG has an excellent response (Vg/Va = 24.8 @ 100 ppm) at room temperature and exhibits a great potential in monitoring pork quality. Ti₃C₂Tx MXene and CuO were characterized by SEM, TEM, EDS, XRD, and XPS to analyze the properties of the materials. The NH₃ sensing performance of the self-powered sensor based on MXene/CuO was greatly improved, and the mechanism of the enhanced sensing properties was systematically discussed.