Two-dimensional Ti₃C₂ MXene-based nanostructures for emerging optoelectronic applications

Since the first discovery of Ti₃C₂ in 2011, two-dimensional (2D) transition-metal carbides, carbonitrides and nitrides, known as MXenes, have attracted significant attention. Due to their outstanding electronic, optical, mechanical, and thermal properties, versatile structures and surface chemistries, Ti₃C₂ MXenes have emerged as new candidates with great potential for applications in optoelectronic devices, such as photovoltaics, photodetectors and photoelectrochemical devices. The excellent metallic conductivity, high anisotropic carrier mobility, good structural and chemical stabilities, high optical transmittance, excellent mechanical strength, tunable work functions, and wide range of optical absorption properties of Ti₃C₂ MXene nanostructures are the key to their success in a number of electronic and photonic device applications. Herein, we summarize the fundamental properties and preparation of pure Ti₃C₂ MXenes, functionalized Ti₃C₂ MXenes and their hybrid nanocomposites, as well as their optoelectronic applications. In the end, the perspective and current challenges of Ti₃C₂ MXenes toward the development of advanced MXene-based nanostructures are briefly discussed for future optoelectronic applications.