Vanadium(III) oxide catalyzes the direct fluorination of C(sp³)-H groups with Selectfluor. This reaction is operationally simple. The catalyst and the reaction byproduct can be removed easily by filtration. Using this method, a fluorine atom can be introduced to the tertiary position of 1,4-cineole and L-menthone selectively.
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Xia et al. (2014) studied this question.
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