PulseExploreJournal ClubDebatesTrendingResearchersJournals
Instagram
HomeExploreJournal ClubTrending
Synapse
⌘+K
Synapse
April 12, 2026Journal of Structural Chemistry0 citations

Beyond Phosphorus: Diazaadamantane and Bispidine Analogs of RAPTA-C and RAED-C

View Full Paper
AMA. V. Medved′koITI. A. TroshinMMM. E. Minyaev

Key Points

  • To prepare and characterize new half sandwich ruthenium complexes with diazaadamantane and bispidine derivatives.
  • Synthesis of half sandwich ruthenium complexes
  • Characterization via single crystal XRD
  • Analysis of complex structures including mononuclear and dinuclear forms
  • New complexes with diazaadamantane and bispidine are successfully synthesized and characterized.
  • 5,7-dimethyl-1,3-diazaadamantane forms both mononuclear and dinuclear complexes with ruthenium.
  • Crystal structures reveal non-typical angles for hydrogen atoms at nitrogen atoms in bispidine complexes.

Abstract

Half sandwich ruthenium complexes with 5,7-dimethyl-1,3-diazaadamantane-6-one, 5,7-dimethyl-1,3-diazaadamantane, 1,5-dimethyl-3,7-diazabicyclo3.3.1nonan-9-one, and 1,5-dimethyl-3,7-diazabicyclo 3.3.1nonane are prepared for the first time; their crystal structures are determined by single crystal XRD. It is established that 5,7-dimethyl-1,3-diazaadamantane can form both mononuclear and dinuclear complexes with ruthenium. In the bispidine complexes, hydrogen atoms at the nitrogen atoms are oriented at a non-typical angle.

Ask AI
Helpful
Bookmark
Share
View Full Paper

Cite This Study

Medved′ko et al. (2026) studied this question.

synapsesocial.com/papers/69db37254fe01fead37c515chttps://doi.org/10.1134/s0022476626030054
Ask AI
Helpful
Bookmark
Share
View Full Paper

Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1Anti‐Amyloid Aggregation and Anti‐Hyperglycemic Activities of Novel Ruthenium Uracil Schiff Base Compounds2024 · 1 citations
  2. 2Coligand-Dependent Cellular Effects and DNA/BSA Binding of Ruthenium(II) Tris(pyrazolylmethane) Complexes2025 · 4 citations
  3. 3Pyrazine-Coordinated Dinuclear and Mononuclear Ruthenium Complexes Formed via the Conversion of the Triply Chlorido-Bridged Diruthenium(II) Complex2024 · 1 citations
  4. 4TETRAIMINE DIRUTHENIUM COMPLEX: SYNTHESIS, CHARACTERIZATION, ANTIMICROBIAL ACTIVITY AND SARS-COV-2 MOLECULAR DOCKING STUDIES2026
  5. 5Catalytic reactions promoted by metal complexes stabilized by 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. A brief survey of recent results2024 · 1 citations