PulseExploreJournal ClubDebatesTrendingResearchersJournals
Instagram
HomeExploreJournal ClubTrending
Synapse
⌘+K
Synapse
April 12, 2026Chemical Science1 citationsOpen Access

Linker Desymmetrisation Directs Low-polar Cages in an Anion-Pillared MOF for Acetylene and Ethylene Purification from Ternary Mixtures

JWJun-Jie WuPZPeng‐Dan ZhangXWXue-Qian Wu

Key Points

  • This research aims to optimize anion organization in metal-organic frameworks for effective gas purification.
  • Synthesis of anion-pillared metal-organic frameworks (APMOFs)
  • Desymmetrisation of linkers
  • Characterization of pore environments
  • Purification tests with acetylene and ethylene
  • Successfully enhanced purification efficiency for acetylene and ethylene
  • Demonstrated a reduction in polar interactions within the framework
  • Showed significant improvements in gas selectivity and adsorption capacity

Abstract

Anion-pillared metal-organic frameworks (APMOFs) constitute a promising class of porous adsorbents, yet precise organization of anionic groups to maximize their strong electronegative character while circumventing highly polar pore environments and...

Ask AI
Helpful
Bookmark
Share
View Full Paper

Cite This Study

Wu et al. (2026) studied this question.

synapsesocial.com/papers/69db37964fe01fead37c58d6https://doi.org/10.1039/d6sc00819d
Ask AI
Helpful
Bookmark
Share
View Full Paper