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June 6, 2011

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Osmium and Ruthenium Catalysts for Dehydrogenation of Alcohols

MBMarcello BertoliWilfrid Laurier University ACA. ChoualebCentre National de la Recherche Scientifique ALAlan J. LoughUniversity of Toronto

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Resumen

A series of pincer-type complexes of Os and Ru have been synthesized and investigated in catalytic alcohol dehydrogenation. The hydrides OsHCl(CO)HN(C2H4PiPr2)2 and OsH2(CO)HN(C2H4PiPr2)2 possess good air, moisture, and thermal stability and are outstanding versatile dehydrogenation catalysts for primary alcohols for reactions of transfer hydrogenation, dehydrogenative coupling, and amine alkylation.

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Cite This Study

Bertoli et al. (Mon,) studied this question.

synapsesocial.com/papers/69dcb3b2f3d3790cb713384d https://doi.org/https://doi.org/10.1021/om200437n

Osmium and Ruthenium Catalysts for Dehydrogenation of Alcohols | Synapse