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Majority rules: “Chiral amplification” in asymmetric transformations can be realized if a helical supramolecular polymer, derived from the substrate (S), obeys the “majority rule” in determining its handedness. This concept works properly for the asymmetric transformation of a chirality-memorizing D2-symmetric saddle-shaped porphyrin.
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Toyofuku et al. (2007) studied this question.
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