In one fell swoop: Stannylated allyl carbonates allow the highly stereoselective synthesis of metalated peptides, which can be further modified by Stille coupling. Tin–iodine exchange generates iodinated peptides which also can be used for CC coupling reactions. Therefore, only one stereoselective reaction is necessary to generate a wide range of different peptides in stereochemically pure form.
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Deska et al. (2007) studied this question.
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